The compounds of phosphorus

Phosphorus is a nonmetallic chemical element with symbol P and atomic number 15. A multivalent pnictogen, phosphorus as a mineral is almost always present in its maximally oxidised state, as inorganic phosphate rocks. Elemental phosphorus exists in two major forms—white phosphorus and red phosphorus—but due to its high reactivity, phosphorus is never found as a free element on Earth.

 

There is some compounds containing phosphorus, oxygen (known as oxides), hydrogen (known as hydrides), and some other compounds of phosphorus. For each compound, a formal oxidation number for phosphorus is given,  In compounds of phosphorus (where known), the most common oxidation numbers of phosphorus are: 5, 3, and -3.

 

1. Hydrides

The term hydride is used to indicate compounds of the type MxHy and not necessarily to indicate that any compounds listed behave as hydrides chemically.

 

Phosphine: PH3

Diphosphorus tetrahydride: P2H4

 

2. Fluorides

Phosphorus trifluoride: PF3

Phosphorus pentafluoride: PF5

Diphosphorus tetrafluoride: P2F4

 

3. Chlorides

Phosphorus trichloride: PCl3

Phosphorus pentachloride: PCl5

Diphosphorus tetrachloride: P2Cl4

Phosphorus oxychloride: POCl3

Dichlorvos: (CH3O)2P(O)OCH=CCl2

 

4. Bromides

Phosphorus pentabromide: PBr5

Diphosphorus tetrabromide: P2Br4

Dimethyl-1,2-dibromo-2,2-dichlorethyl phosphate: (CH3O)2P(O)OCHBrCBrCl2

 

5. Iodides

Phosphorus triiodide: PI3

Diphosphorus tetraiodide: P2I4

 

6. Oxides

Tetraphosphorus decaoxide: P4O10

Tetraphosphorus hexaoxide: P4O6

 

7. Sulfides

Phosphorus pentasulfide: P2S5

Phosphorus pentasulfide: P4S10

Phosphorus Trisulfide: P2S3

Sulprofos: C12H19O2PS3

Azinphos-methyl: C10H12O3PS2N3 [(CH3O)2P(S)SCH2(N3C7H4O)]

Fenthion: C10H15O3PS [(CH3O)2P(S)OC6H3(CH3)SCH3]

Fonofos: C10H15OPS2

Chlorpyrifos: C9H11Cl3NO3PS

Demeton: (C2H5O)2PSOC2H4SC2H5

Dimethyl glycol phthalate: C12H21N2O3PS

Disulfoton: C8H19O2PS3 [(C2H5O)2P(S)S(CH2)2SC2H5]

EPN: C14H14O4NSP [(C2H5O(C6H5)P(S)OC6H4NO2)]

Ethion: [(C2H5O)2P(S)S]2CH2

Ethyl butyrate: [(CH3CH2O)2PS]2O

Ethyl parathion: (C2H5O)2P(S)OC6H4NO2

Fenamiphos: C13H22NO3PS

Fensulfothion: C11H17O4PS2 [(C2H5O)2P(S)OC6H4S(O)CH3]

Malathion: C10H19O6PS2 [(CH3O)2P(S)SCH(COOC2H5)CH2COOC2H5]

Methyl demeton: C6H15O3PS2 [(CH3O)2P(S)O[CH2]2SCH2CH3]

Methyl parathion: (CH3O)2P(S)OC6H4NO2

Phorate: (C2H5O)2P(S)SCH2SC2H5

 

8. Others

Phosphoric acid: H3PO4

Calcium phosphide: Ca3P2

Dibutyl phosphate: (C4H9O)2(OH)PO

Dicrotophos: C8H16NO5P

Monocrotophos: C7H14NO5P [(CH3O)2P(O)OC(CH3)=CHC(O)NHCH3]

Phenylphosphine: C6H5PH2

Triphenylphosphine: P(C6H5)3

Tetraethyl pyrophosphate: [(CH3CH2O)2PO]2O

Tetrasodium pyrophosphate: Na4P2O7

Tri-Phenyl Phosphate: (C6H5O)3PO

Tributyl phosphate: (CH3[CH2]3O)3PO

Tributyl phosphate: C12H27O4P

Trimethyl phosphite: (CH3O)3P

Triorthocresyl phosphate: (CH3C6H40)3PO

Leave a comment